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When Ive looked at literature on methylene blue, Ive only found one case report of toxicity in humans

There is insufficient evidence regarding the safety of glutathione injection during pregnancy or breastfeeding

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GHK is a tripeptide glycyl-L-histidyl-L-lysine isolated from human plasma in 1973 by Loren Pickart and Malcolm Thaler, who were investigating why serum from younger donors supported cultured liver cells better than serum from older donors